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URLQuote
The effect of pressure on NOx emission during char particle combustion was examined in chemical-reaction control and diffusion control regimes. A fixed bed was used for batch testing under 0.1−1.6 MPa. It was found that with increasing pressure, NOx emission decreased extremely, when char combustion rate was controlled by reactant gas diffusion into the char particle at high temperature. The extent to which NOx was reduced in char particles strongly influenced the NOx emission from char pressurized combustion. Pressure increased residence time for diffusion of NOx throughout the char particle and consequently further increased the reduction of NOx in the char particle. Both pressure and temperature strongly influenced the conversion of fuel-N in char to NOx. When pressure was raised from 0.1 to 1.1 MPa, the conversion of fuel-N to NOx fell from 0.18 to 0.06 at 973 K, and from 0.68 to 0.13 at 1173 K. NOx emissions were lower when large char particles were combusted than when small ones were combusted. It was also observed that practically no N2O was formed in to any extent in the char particle.
URLQuote
Abstract
The effect of fuel–air unmixedness on NOx emissions from industrial lean premixed gas turbine burners fueled
with natural gas is analyzed in the pressure range from 1 to 30 bar. The analysis is based on a model where
NOx production is split, according to a Damköhler number criterion, into a “prompt” (fast) contribution generated
within the very narrow instantaneous heat release region (flamelet) and a “postflame” (slow) one, generated in
the combustion products. Using GRI3.0 chemical kinetics, it is found that (a) the prompt NOx contribution is
approximately a factor of 3 less sensitive to adiabatic flame temperature variations than postflame NOx and (b)
prompt and postflame NOx change with pressure respectively according to an exponent αPR −0.45 and αPF
0.67. It is shown that total NOx emissions change from being mostly of prompt type at 1 bar to being mostly
of postflame type at 30 bar, so that the effect of fuel–air unmixedness on NOx emissions significantly increases
with increasing pressure. The combination of these findings yields a negative NOx pressure exponent under fully
premixed conditions across a rather large range of equivalence ratios but a positive one for levels of fuel–air
unmixedness typical of industrial burners. This result is confirmed by the application of the NOx model in the
large eddy simulation of the ALSTOM EV double cone burner, which gives, in line with experimental data, an
NOx pressure exponent growing, with equivalence ratio, from 0.1 to 0.67.
© 2007 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
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File Name | File Size | Posted by | Date | ||
---|---|---|---|---|---|
rotary-cup-burner1.jpg | 49.7 KB | open | download | lohring | 06/28/2014 | Read message |
31823-sub1.jpg | 137.4 KB | open | download | lohring | 06/28/2014 | Read message |
boiler.jpg | 56.7 KB | open | download | steamerandy | 06/29/2014 | Read message |
boiler1.jpg | 48.6 KB | open | download | steamerandy | 06/29/2014 | Read message |
sesboiler.jpg | 81.3 KB | open | download | steamerandy | 06/30/2014 | Read message |
scan10001.jpg | 95 KB | open | download | frustrated | 07/01/2014 | Read message |
nsds_turbine_chart.pdf | 676.4 KB | open | download | Jim Crank | 01/27/2015 | Read message |